scph101.bin has still red tick
So either you have the wrong md5 in this file, or it is renamed wrong (it is case sensitive).
is it possible to know which bios a game does need? For instance: Legend of Mana requires scph5500?
I don't know which ROM requires which BIOS, but if the game doesn't work, and you're missing a BIOS, first test adding the correct BIOS, if that doesn't work then we'll try other possibilities.