It works fine with Recalbox (I tested in USB mode). And it looks really cute.
But I can't recommend this controller to any gamer, even though it's linked on the Recalbox site store.
For US$43 (!!!), I expected something very good indeed. But its d-pad is a disgrace. There are better d-pads on aftermarket controllers that cost $10. Even on simple games that don't require precision I find that this d-pad fails me and easily registers the wrong clicks. It is not fun to fail at a game because the controller sucks.
Also, its lights keep flashing in whatever mode its in, whether USB or Bluetooth. It's annoying.
There are good things about the 8Bitdo: it supports many different compatibility modes (hard to configure) that could help emulation freaks who need to work with Macs and Android and other specialized platforms. But none of those are important to Recalbox users. At the end of the day, if the d-pad sucks, it just plain sucks.
If you are looking for an aftermarket controller, I had good results with the $20 Gamesir G3s (it also has a Bluetooth version, though I don't know if that will work with Recalbox). Its d-pad isn't as good as PlayStation or even Nintendo controllers, but it's at least as good if not better than the Xbox 360. And it works with Android, too.
Anyway, please save your money and don't buy from 8Bitdo if you really want to enjoy your games!