While Recalbox with Pi2Scart doesn't automatically detect your TV type, it does default to a safe mode compatible with both 4:3 and 16:9 displays. You'll likely need manual adjustments for optimal output on a specific CRT, but the initial settings prioritize preventing image stretching or cropping on either aspect ratio.
This means you'll see black bars on a widescreen TV, but your classic games will appear correctly on a 4:3 CRT without further configuration.